610796-53-7Relevant academic research and scientific papers
Intermolecular Aminoallylation of Alkenes Using Allyl-Oxyphthalimide Derivatives: A Case Study in Radical Polarity Effects
Lardy, Samuel W.,Schmidt, Valerie A.
, p. 6796 - 6799 (2019)
A case study on the polarity effects of radical mediated intermolecular alkene aminoallylation is presented herein. This radical group transfer method pairs vinyl ethers with electronically deficient allyl-oxyphthalimide derivatives to give difunctionalized products while illustrating the guiding effects of polarity on this radical reactivity.
2-Phenylthio-3-bromopropene, a valuable synthon, easily prepared by a simple rearrangement
Chen, Wenbo,Zhao, Xiaoming,Lu, Long,Cohen, Theodore
, p. 2087 - 2090 (2007/10/03)
Treatment of allyl phenyl sulfide with bromine, followed by aqueous sodium hydroxide, provides a good yield of 2-phenylthio-3-bromopropene 2 via a mechanism that is elucidated by isolation of the 1,3-dibromo-2-(phenylthio) propene intermediate 7. Three us
Pt-catalyzed regio- and stereoselective thienylthiolation of alkynes
Hirai, Takayoshi,Kuniyasu, Hitoshi,Kambe, Nobuaki
, p. 1148 - 1149 (2007/10/03)
The Pt-catalyzed decarbonylative thienylthiolation of terminal alkynes by thienylthioesters took place regio- and stereoselectively under toluene reflux to give vinylsulfides with cis-thienyl group at β-carbon in moderate to good yields.
2-Phenylthioallylation of aldehydes with allyl phenyl sulfides via dibromination, followed by dehydrobromination
Masuyama, Yoshiro,Sano, Takehiro,Oshima, Michihito,Kurusu, Yasuhiko
, p. 1679 - 1680 (2007/10/03)
2-Phenylthioallyl bromides, derived from allyl phenyl sulfides via dibromination, followed by dehydrobromination, cause the 2-phenylthioallylation of aldehydes with tin(II) iodide, tetrabutylammonium iodide and sodium iodide in 1,3-dimethylimidazolidin-2-
