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Palladium, bromochlorobis(triphenylphosphine)- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 61111-81-7 Structure
  • Basic information

    1. Product Name: Palladium, bromochlorobis(triphenylphosphine)-
    2. Synonyms:
    3. CAS NO:61111-81-7
    4. Molecular Formula: C36H30BrClP2Pd
    5. Molecular Weight: 746.359
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 61111-81-7.mol
  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Palladium, bromochlorobis(triphenylphosphine)-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Palladium, bromochlorobis(triphenylphosphine)-(61111-81-7)
    11. EPA Substance Registry System: Palladium, bromochlorobis(triphenylphosphine)-(61111-81-7)
  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 61111-81-7(Hazardous Substances Data)

61111-81-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 61111-81-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,1,1,1 and 1 respectively; the second part has 2 digits, 8 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 61111-81:
(7*6)+(6*1)+(5*1)+(4*1)+(3*1)+(2*8)+(1*1)=77
77 % 10 = 7
So 61111-81-7 is a valid CAS Registry Number.

61111-81-7Downstream Products

61111-81-7Relevant articles and documents

A Combined Experimental/Computational Study of the Mechanism of a Palladium-Catalyzed Bora-Negishi Reaction

Campos, Jesús,Nova, Ainara,Kolychev, Eugene L.,Aldridge, Simon

, p. 12655 - 12667 (2017)

Experimental and computational efforts are reported which illuminate the mechanism of a novel boron version of the widespread Negishi coupling reaction that offers a new protocol for the formation of aryl/acyl C?B bonds using a bulky boryl fragment. The role of nucleophilic borylzinc reagents in the reduction of the PdII pre-catalysts to Pd0 active species has been demonstrated. The non-innocent behavior of the PPh3 ligands of the [Pd(PPh3)2Cl2] pre-catalyst under activation conditions has been probed both experimentally and computationally, revealing the formation of a trimetallic Pd species bearing bridging phosphide (PPh2?) ligands. Our studies also reveal the monoligated formulation of the Pd0 active species, which led us to synthesize related (η3-indenyl)Pd-monophosphine catalysts which show improved catalytic performances under mild conditions. A complete mechanistic proposal to aid future catalyst developments is provided.

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