61145-11-7Relevant academic research and scientific papers
The [4+2]-Cycloaddition of α-Nitrosoalkenes with Thiochalcones as a Prototype of Periselective Hetero-Diels–Alder Reactions—Experimental and Computational Studies
Mlostoń, Grzegorz,Urbaniak, Katarzyna,Jasiński, Marcin,Würthwein, Ernst-Ulrich,Heimgartner, Heinz,Zimmer, Reinhold,Reissig, Hans-Ulrich
supporting information, p. 237 - 248 (2019/11/29)
The [4+2]-cycloadditions of α-nitrosoalkenes with thiochalcones occur with high selectivity at the thioketone moiety of the dienophile providing styryl-substituted 4H-1,5,2-oxathiazines in moderate to good yields. Of the eight conceivable hetero-Diels–Ald
A new method for the generation of α-nitrosoolefins from ketooximes and its application to the synthesis of 5,6-dihydro-4H-1,2-oxazine derivatives [1]
Gaonkar,Rai, K. M. Lokanatha
, p. 877 - 881 (2007/10/03)
Reaction of ketooximes containing α-methylene group with chloramine-T followed by treatment with triethylamine leads to the formation of α-nitrosoolefins via α-nitrosochloride, which can react in situ intermolecularly with olefinic compounds to produce 5,
Theoretical Prediction and Experimental Tests of Conformational Switches in Transition States of Diels-Alder and 1,3-Dipolar Cycloadditions to Enol Ethers
Liu, Jian,Niwayama, Satomi,You, Ying,Houk
, p. 1064 - 1073 (2007/10/03)
Transition structures for the cycloadditions of butadiene, acrolein, nitrosoethylene, and methyl-enenitrone to 1-butene, silyl vinyl ether, and methyl vinyl ether have been located using ab initio RHF theory with the 3-21G basis set and with density funct
A New Mode of Addition of α-Nitrosostyrenes
Mackay, Donald,Watson, Kenneth N.
, p. 775 - 776 (2007/10/02)
Treatment of the two known (oxazine) 1,4-adducts of α-nitrosostyrene and either 2,5-dimethylfuran or cyclopentadiene with further nitrosostyrene gives nitrones, products of 1,3-addition at the oximino C=N.
