61154-45-8

Basic information

• Product Name: 2-(2-Oxopropyl)cycloheptanone
• Synonyms: 2-(2-Oxopropyl)cycloheptanone
• CAS NO: 61154-45-8
• Molecular Formula: C₁₀H₁₆O₂
• Molecular Weight: 168.23
• Mol File: 61154-45-8.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 128 °C(Press: 12 Torr)
• Appearance: /
• Density: 1.0469 g/cm3
• CAS DataBase Reference: 2-(2-Oxopropyl)cycloheptanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-Oxopropyl)cycloheptanone(61154-45-8)
• EPA Substance Registry System: 2-(2-Oxopropyl)cycloheptanone(61154-45-8)

Safety Data

• Hazardous Substances Data: 61154-45-8(Hazardous Substances Data)

Upstream product

• 4401-23-4 octahydro-2H-cyclohepta[b]furan-2-one 
• 917-54-4 methyllithium 
• 116-11-0 2-Methoxypropene 
• 1056246-49-1 2-bromocycloheptanone 
• 220043-96-9 2-(prop-2-yn-1-yl)cycloheptanone 
• 14092-11-6 1-pyrrolidino-1-cycloheptene 
• 598-31-2 1-bromoacetone 
• 61154-43-6 1-(2-Hydroxy-cycloheptyl)-propan-2-one 
• 6114-69-8 N-cyclohexyl-N-cycloheptylidenamine 
• 76634-95-2 3-chloro-2-(trimethylsilyloxy)prop-1-ene 
• 889451-80-3 2-(2-phenylsulfanyl-allyl)-cycloheptanone 
• 65700-06-3 percarbonate de O,O-tert-butyle et O-isopropyle 
• 502-42-1 cycloheptanone 
• 105104-40-3 Okahara's reagent 

Downstream Products

• 1311376-92-7 1-(4-chlorobenzyl)-2-methyl-1,4,5,6,7,8-hexahydrocyclohepta[b]pyrrole 
• 1311376-60-9 2-(1-(4-chlorobenzyl)-2-methyl-1,4,5,6,7,8-hexahydrocyclohepta[b]pyrrol-3-yl)-N-(3-chlorophenyl)-2-oxoacetamide 
• 769-86-8 2-methylazulene 

Relevant articles and documents

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Intramolecular Schmidt Reaction of Vinyl Azides with Cyclic Ketones

Cyclic ketones tethered with a vinyl azide group undergo a Schmidt-hydrolysis sequence to give secondary lactams bearing a ketone side chain. Secondary lactams are obtained in a regioselective manner that is not possible in a conventional Schimdt reaction. In addition to the well-documented C-2 nucleophilicity, the N nucleophilicity of vinyl azide disclosed in this work opens a new direction for reaction invention involving vinyl azides.

2-Phenylthio-3-bromopropene, a valuable synthon, easily prepared by a simple rearrangement

Treatment of allyl phenyl sulfide with bromine, followed by aqueous sodium hydroxide, provides a good yield of 2-phenylthio-3-bromopropene 2 via a mechanism that is elucidated by isolation of the 1,3-dibromo-2-(phenylthio) propene intermediate 7. Three us