61203-99-4

Usage

Chemical Properties

White crystalline

Uses

Intermediates of Liquid Crystals

Upstream product

• 73163-49-2 4-(trans-4-propylcyclohexyl)benzamide 
• 71-43-2 benzene 
• 81005-00-7 trans-4-(4-Propylcyclohexyl)benzoesaeurechlorid 
• 88069-92-5 cis-4-propionyl-1-phenylcyclohexane 
• 88069-93-6 trans-4-propionyl-1-phenylcyclohexane 
• 65355-29-5 4-(trans-4'-propylcyclohexyl)-benzoic acid 
• 78531-61-0 1-[4-(4-Propyl-cyclohexyl)-phenyl]-ethanone 
• 88069-99-2 1-(4-Phenyl-cyclohexyl)-propan-1-ol 
• 88069-94-7 1-Phenyl-4-propyl-cyclohexanol 
• 61203-94-9 trans-4-propyl-1-phenylcyclohexane 
• 79951-21-6 1-(4-propylcyclohex-1-enyl)benzene 
• 78531-57-4 (4-Propylidene-cyclohexyl)-benzene 
• 88069-91-4 1-propionyl-2-chlorocyclohexane 
• 40649-36-3 4-propyl-cyclohexanone 

Downstream Products

• 78531-61-0 1-[4-(4-Propyl-cyclohexyl)-phenyl]-ethanone 
• 95149-33-0 1-[4-(4-Propyl-cyclohexyl)-phenyl]-propan-1-one 
• 65355-29-5 4-(trans-4'-propylcyclohexyl)-benzoic acid 
• 151105-68-9 1-Bromomethyl-4-(4-propyl-cyclohexyl)-benzene 
• 93205-73-3 [4-(4-Propyl-cyclohexyl)-phenyl]-methanol 
• 101183-48-6 4-Chloro-2-fluoro-1-{2-[4-(4-propyl-cyclohexyl)-phenyl]-ethyl}-benzene 

Relevant academic research and scientific papers

Hydrogenation of alkenes via cooperative hydrogen atom transfer

Radical hydrogenation via hydrogen atom transfer (HAT) to alkenes is an increasingly important transformation for the formation of thermodynamic alkane isomers. Current single-catalyst methods require stoichiometric oxidant in addition to hydride (H-) source to function. Here we report a new approach to radical hydrogenation: cooperative hydrogen atom transfer (cHAT), where each hydrogen atom donated to the alkene arrives from a different catalyst. Further, these hydrogen atom (H?) equivalents are generated from complementary hydrogen atom precursors, with each alkane requiring one hydride (H-) and one proton (H+) equivalent and no added oxidants. Preliminary mechanistic study supports this reaction manifold and shows the intersection of metal-catalyzed HAT and thiol radical trapping HAT catalytic cycles to be essential for effective catalysis. Together, this unique catalyst system allows us to reduce a variety of unactivated alkene substrates to their respective alkanes in high yields and diastereoselectivities and introduces a new approach to radical hydrogenation.

SYNTHESIS OF TRANS-4-ALKYL-1-PHENYLCYCLOHEXANES AND THEIR DERIVATIVES

The alkylation of benzene by 1-alkanoyl-2-chlorocyclohexanes and 1-alkanoyl-1-cyclohexenes leads to the formation of cis- and trans-4-alkanoyl-1-phenylcyclohexanes, the yields of which increase with increase in the reaction temperature. trans-4-Alkyl-1-phenylcyclohexanes were obtained from 4-alkanoyl-1-phenylcyclohexanes and also from the products from the reaction of 4-alkylcyclohexanones with phenylmagnesium bromide.Some mesomorphous derivatives of these hydrocarbons were synthesized.

CONVENIENT SYNTHESIS OF 4-(TRANS-4 prime -N-ALKYLCYCLOHEXYL) BENZOIC ACIDS.

A convenient method of obtaining 4-(trans-4 prime -n-alkylcyclohexyl) benzoic acids from alkanoyl chlorides, cyclohexane and benzene is described. Homologous series of above mentioned acids and their nitriles with alkyl tail 2 to 10 carbon atoms were prepared and temperatures of their phase transitions were determined.