61222-94-4

Basic information

• Product Name: Benzenepropanenitrile, a-(2-furanylmethylene)-b-oxo-
• CAS NO: 61222-94-4
• Molecular Formula: C14H9NO2
• Molecular Weight: 223.231
• Mol File: 61222-94-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzenepropanenitrile, a-(2-furanylmethylene)-b-oxo-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenepropanenitrile, a-(2-furanylmethylene)-b-oxo-(61222-94-4)
• EPA Substance Registry System: Benzenepropanenitrile, a-(2-furanylmethylene)-b-oxo-(61222-94-4)

Safety Data

• Hazardous Substances Data: 61222-94-4(Hazardous Substances Data)

Upstream product

• 98-01-1 furfural 
• 614-16-4 Benzoylacetonitrile 
• 110-89-4 piperidine 
• 64-17-5 ethanol 

Downstream Products

• 99941-37-4 4-Furan-2-yl-3-methyl-6-phenyl-1,4-dihydro-pyrano[2,3-c]pyrazole-5-carbonitrile 
• 87736-65-0 3-(3-methyl-5-oxo-1H-pyrazol-4-ylidene)-3-phenylpropiononitrile 
• 99941-38-5 4-Furan-2-yl-3-methyl-1,6-diphenyl-1,4-dihydro-pyrano[2,3-c]pyrazole-5-carbonitrile 
• 1378998-64-1 C₂₀H₁₉NO₃ 
• 1253801-80-7 C₂₃H₁₅NO₃ 

Relevant articles and documents

Reactions with 2-aminobenzimidazole: Synthesis of several new pyrimido[1,2-a]benzimidazole derivatives

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Magnesium Halide-Catalyzed Synthesis of Oxaspiro[2.5]octenes from a Methylenecyclopropane and Acyl Cyanoalkenes

MgX2-catalyzed annulation of methylenecyclopropanes with acyl cyanoalkenes was accomplished to give oxaspiro[2.5]octenes in excellent yields. The reaction proceeded through a rare intramolecular oxa-Michael addition of Mg enolate. The oxaspiro

Diels-Alder reactions of acyclic α-cyano α,β-alkenones: a new approach to highly substituted cyclohexene system

The Diels-Alder reactions of a variety of acyclic α-cyano α,β-unsaturated ketones 8 have been investigated. With the assistance of boron trichloride, these compounds were found to undergo the cycloaddition readily with dienes to give the corresponding add

Replacement Substituent Constants for Simple Heterocycles

13C nmr absorptions are reported for the β-vinylic carbon atoms in 15 series of ethylenes bearing heterocyclic substituents.The data are used to establish the best single-parameter substituent constants, ?13, for the various heterocycles as replacements for para-substituted benzenes.Also reported are replacement dual substituent constants, including ?I and the various ?R scales needed in the Taft DSP treatment and those for F and R used in the Swain-Lupton treatment.Values of ?13, F, R, ?I, and ?Ro, respectively, for the various heterocycles as replacements for para-substituted benzenes are as follows: 2-furyl, -1.01 , 0.99, -2.51, 0.65, -0.60; 2-pyrryl, -2.53, 0.52, -5.09, -0.16, -0.62; 2-thienyl, -0.79, 2.49, -3.60, 1.82, -1.08; 3-thienyl, -0.40, 1.04, -1.57, 0.59, -0.39; 2-pyridyl, 0.88, 2.09, -0.24, 1.65, -0.45; 3-pyridyl, 0.60, 0.57, 0.63, 0.35, 0.04; and 4-pyridyl, 1.18, 1.22, 1.09, 0.92, -0.01.The DSP-NLR method of analysis is explored using electron demand parameters, ε, as determined for the vinylic side chains in para-substituted styrenes.