6124-91-0

Basic information

• Product Name: rel-2α*-Propyl-3β*-methyloxirane
• Synonyms: rel-2α*-Propyl-3β*-methyloxirane
• CAS NO: 6124-91-0
• Molecular Formula: C₆H₁₂O
• Molecular Weight: 100.16
• Mol File: 6124-91-0.mol
• Article Data: 5

Chemical Properties

• Appearance: /
• CAS DataBase Reference: rel-2α*-Propyl-3β*-methyloxirane(CAS DataBase Reference)
• NIST Chemistry Reference: rel-2α*-Propyl-3β*-methyloxirane(6124-91-0)
• EPA Substance Registry System: rel-2α*-Propyl-3β*-methyloxirane(6124-91-0)

Safety Data

• Hazardous Substances Data: 6124-91-0(Hazardous Substances Data)

Upstream product

• 7688-21-3 cis-2-hexene 
• 4050-45-7 trans-2-hexene 
• 628-92-2 Cycloheptene 
• 592-43-8 2-hexene 

Downstream Products

• 13269-52-8 trans-3-Hexene 
• 3298-40-6 mesoxalate de methyle 
• 623-37-0 n-hexan-3-ol 
• 626-93-7 n-hexan-2-ol 
• 7688-21-3 cis-2-hexene 
• 4050-45-7 trans-2-hexene 
• 4798-44-1 1-hexene-3-ol 

Relevant articles and documents

Epoxidation of alkenes and their derivatives over Ti-YNU-1

The catalytic properties of Ti-YNU-1 for the epoxidation of various alkenes and their derivatives have been investigated in detail, and further were made a comparison with those of Ti-Beta. The much higher efficiency of Ti-YNU-1 than Ti-Beta was observed in catalyzing the epoxidation of alkenes and their electron-rich analogues. Although it was less active in the epoxidation of α,β-unsaturated ketones, it showed much higher stability. In contrast, Ti leaching from the framework sites occurred to Ti-Beta, and the leaching degree increased with the carbon number of ketones. It was also shown that the catalytic conditions, including the Ti content in samples, H 2O2/substrate ratio, reaction temperature and time, acid washing and catalyst amount, significantly influenced the activity, selectivity and H2O2 efficiency. Co-oxidation of different alkenes led to the activity and epoxide selectivity being different from those obtained in the oxidation of single olefin as a result of the differences in adsorption properties of substrates over various titanosilicates, which affected the diffusion of substrate molecules and accounted for the unique shape-selectivity of Ti-YNU-1.

Selective alkene oxidation with H2O2 and a heterogenized Mn catalyst: Epoxidation and a new entry to vicinal cis-diols

Covalent anchoring of 1,4-dimethyl-1,4,7-triazacyclononane on silica gel is the first step in the preparation of a heterogenized Mn catalyst. When H2O2 is used as the oxidant, this material can catalyze the vicinal cis- dihydroxylation of disubstituted olefins, as shown schematically here. Both enantiomers of the product are obtained.

MONOOXYGENASE-LIKE OXIDATIONS OF OLEFINS AND ALKANES CATALYZED BY MANGANESE PORPHYRINS : COMPARISON OF SYSTEMS INVOLVING EITHER O2 AND ASCORBATE OR IODOSYLBENZENE

A biphasic system using a manganese porphyrin as a catalyst and sodium ascorbate as a reducing agent is able to activate dioxygen and to oxidize olefins selectively into epoxides and alkanes into alcohols and ketones.Its properties and specifities are shown to be different from those of the manganese porphyrin-iodosylbenzene system, suggesting that a manganese -oxo complex is not involved in these O2-dependent oxidations.