612481-30-8

Basic information

• Product Name: (2aS,4R,4aR,7aR,7bR)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-phenyl]-5-methylene-4-vinyl-decahydro-indeno[7,1-bc]furan-2-ol
• Synonyms: (2aS,4R,4aR,7aR,7bR)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-phenyl]-5-methylene-4-vinyl-decahydro-indeno[7,1-bc]furan-2-ol
• CAS NO: 612481-30-8
• Molecular Weight: 442.671
• Mol File: 612481-30-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2aS,4R,4aR,7aR,7bR)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-phenyl]-5-methylene-4-vinyl-decahydro-indeno[7,1-bc]furan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2aS,4R,4aR,7aR,7bR)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-phenyl]-5-methylene-4-vinyl-decahydro-indeno[7,1-bc]furan-2-ol(612481-30-8)
• EPA Substance Registry System: (2aS,4R,4aR,7aR,7bR)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-phenyl]-5-methylene-4-vinyl-decahydro-indeno[7,1-bc]furan-2-ol(612481-30-8)

Safety Data

• Hazardous Substances Data: 612481-30-8(Hazardous Substances Data)

Upstream product

• 612481-28-4 (2aS,4R,4aR,7aR,7bR)-5-Methylene-4-vinyl-decahydro-indeno[7,1-bc]furan-2-ol 
• 612481-27-3 (2aS,4S,4aS,7aR,7bR)-2-Hydroxy-5-methylene-decahydro-indeno[7,1-bc]furan-4-carbaldehyde 
• 177329-71-4 5-Bromo-1-(tert-butyldimethylsilyloxy)-2-methoxybenzene 
• 612481-29-5 (2aS,4R,4aR,7aR,7bR)-5-Methylene-4-vinyl-octahydro-indeno[7,1-bc]furan-2-one 

Downstream Products

• 612481-32-0 (1R,3R,3aS,7aR)-3-[3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-benzyl]-7-methylene-1-vinyl-octahydro-inden-4-one 
• 612481-31-9 (1R,3R,3aS,4R,7aR)-3-[3-(tert-Butyl-dimethyl-silanyloxy)-4-methoxy-benzyl]-7-methylene-1-vinyl-octahydro-inden-4-ol 

Relevant articles and documents

Enantioselective total syntheses of (+)- and (-)-ottelione A and (+)- and (-)-ottelione B. Absolute configuration of the novel, biologically active natural products

Following our recent total synthesis of the biologically potent natural products otteliones A and B in racemic form, we have now accomplished the total synthesis of both the enantiomers of otteliones A and B through an enantiodivergent strategy emanating from the readily available Diels-Alder adduct of cyclopentadiene and p-benzoquinone. These endeavors have led to the elucidation of the absolute configuration of naturally occurring otteliones A and B.