61282-91-5Relevant academic research and scientific papers
Rh-catalyzed novel α-fluoroalkylation of α,β-unsaturated ketones and its mechanism
Sato, Kazuyuki,Ishida, Yoshitaka,Murata, Eriko,Oida, Yumiko,Mori, Yasumitsu,Okawa, Miho,Iwase, Kayoko,Tarui, Atsushi,Omote, Masaaki,Kumadaki, Itsumaro,Ando, Akira
, p. 12735 - 12739 (2007)
Treatment of α,β-unsaturated ketones and fluoroalkyl halides with Et2Zn in the presence of RhCl(PPh3)3 gave novel reductive fluoroalkylation products at the α-position of α,β-unsaturated ketones in moderate to good yields.
HEPTAFLUOROPROPYLATION OF ELECTRON-RICH OLEFINS WITH BIS(HEPTAFLUOROBUTYRIL) PEROXIDE
Yoshida, Masato,Moriya, Koji,Sawada, Hideo,Kobayashi, Michio
, p. 755 - 758 (2007/10/02)
Bis(heptafluorobutyril) peroxide reacted with electron-rich olefins to give the adducts of C3F7CO2 and C3F7 groups in good yields.The peroxide should be the useful reagent for the introduction of heptafluoropropyl moiety into olefins.
