612824-85-8

Basic information

• Product Name: 1-Pentanone, 2-azido-1-(4-methoxyphenyl)-
• CAS NO: 612824-85-8
• Molecular Formula: C12H15N3O2
• Molecular Weight: 233.27
• Mol File: 612824-85-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Pentanone, 2-azido-1-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pentanone, 2-azido-1-(4-methoxyphenyl)-(612824-85-8)
• EPA Substance Registry System: 1-Pentanone, 2-azido-1-(4-methoxyphenyl)-(612824-85-8)

Safety Data

• Hazardous Substances Data: 612824-85-8(Hazardous Substances Data)

Upstream product

• 1671-76-7 p-Methoxyvalerophenon 

Downstream Products

• 612824-88-1 2,5-bis-n-propyl-3,6-bis-(4'-methoxyphenyl)-pyrazine 

Relevant articles and documents

Kinetic diastereomer differentiation in Au(III)- and Bi(III)-catalyzed benzylic arylation: Concise and stereocontrolled synthesis of 2-amino-1,1-diarylalkanes

Benzylic alcohols carrying an adjacent α-nitro or α-azido group on the alkane chain are converted into syn-1,1-diaryl-2-nitro- and 2-azidoalkanes with electron-rich arenes in stereoselective reactions catalyzed by Bronsted and Lewis acids. Gold(III) chloride and bismuth(III) triflate were found to be especially efficient as catalysts, showing kinetically controlled differentiation in the reactivity of diastereomeric α-substituted benzyl alcohols. Applications to therapeutically relevant syn- and anti- 2-amino-1,1-diarylalkanes are projected.