612840-25-2Relevant academic research and scientific papers
Remarkable Change of the Diastereoselection in the Dye-Sensitized Ene Hydroperoxidation of Chiral Alkenes by Zeolite Confinement
Stratakis, Manolis,Kalaitzakis, Dimitris,Stavroulakis, Dimitris,Kosmas, Giannis,Tsangarakis, Constantinos
, p. 3471 - 3474 (2007/10/03)
(Equation presented) The ene reaction of singlet oxygen with chiral trisubstituted alkenes bearing an alkyl and a phenyl group at the stereogenic center is erythro diastereoselective in solution and threo diastereoselective if carried out within zeolite Na-Y. The change of the diastereoselection trend by zeolite confinement is attributed to a synergism of steric effects and cation-π interactions.
