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6129-66-4

4-hydroxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside is a complex organic compound that consists of a phenol group (4-hydroxyphenyl) and a glucose molecule (β-D-glucopyranoside). The glucose molecule is modified with four acetyl groups attached to the hydroxyl groups at positions 2, 3, 4, and 6, which protect the hydroxyl groups and prevent unwanted reactions. 4-hydroxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside is often used in organic synthesis and as an intermediate in the preparation of various pharmaceuticals and natural products. It is a white crystalline solid and is soluble in common organic solvents. The compound is characterized by its molecular formula C21H26O11 and a molecular weight of 454.42 g/mol.

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  • 6129-66-4 Structure

  • Basic information

    1. Product Name: 4-hydroxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside
    2. Synonyms:
    3. CAS NO:6129-66-4
    4. Molecular Formula:
    5. Molecular Weight: 440.404
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 6129-66-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 4-hydroxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(CAS DataBase Reference)
    10. NIST Chemistry Reference: 4-hydroxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(6129-66-4)
    11. EPA Substance Registry System: 4-hydroxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside(6129-66-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 6129-66-4(Hazardous Substances Data)

6129-66-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 6129-66-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 6,1,2 and 9 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 6129-66:
(6*6)+(5*1)+(4*2)+(3*9)+(2*6)+(1*6)=94
94 % 10 = 4
So 6129-66-4 is a valid CAS Registry Number.

6129-66-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name Ph-β-GluOAc

1.2 Other means of identification

Product number -
Other names 4-hydroxyphenyl 2,3,4,6-tetra-O-acetyl-β-D-glucopyranoside

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:6129-66-4 SDS

6129-66-4Relevant articles and documents

Preparation method of glucoside and derivatives thereof

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Paragraph 0030-0031; 0033; 0035; 0038, (2020/04/02)

The invention discloses a preparation method of glucoside and derivatives thereof. According to the method, all hydroxyl groups on a sugar molecule structure are acetylated, a ligand containing phenolic hydroxyl groups is prepared at the same time, then boron trifluoride-diethyl ether is used as a catalyst, the two substances are condensed to obtain tetraacetylated glucoside, and finally acetyl protecting groups are removed to obtain the required glucoside. The method can selectively catalyze hemiacetal hydroxyl of monosaccharide to react with hydroxyl to obtain glucoside, and the product is single. The method is simple in production operation and low in equipment requirement, can be used for synthesizing glucoside and derivatives thereof with similar structures, is green and environment-friendly, and can be used for large-scale production.

Palladium-Catalyzed Chemoselective Negishi Cross-Coupling of Bis[(pinacolato)boryl]methylzinc Halides with Aryl (Pseudo)Halides

Lee, Hyojae,Lee, Yeosan,Cho, Seung Hwan

supporting information, p. 5912 - 5916 (2019/08/20)

We describe a palladium-catalyzed chemoselective Negishi cross-coupling of a bis[(pinacolato)boryl]methylzinc halide with aryl (pseudo)halides. This reaction affords an array of benzylic 1,1-diboronate esters, which can serve as useful synthetic handles f

Synthesis and G-quadruplex binding study of a novel full visible absorbing perylene diimide dye

Din?alp, Haluk,Kizilok, ?evki,Birel, ?zgül Hakli,I?li, Siddik

experimental part, p. 40 - 48 (2012/06/18)

A novel perylene diimide dye containing glucopyranosyl groups in 1- and 7-positions of the perylene ring has been synthesized and characterized to obtain highly efficient and stable photosensitized material in photodynamic therapy. Solvatochromic studies

Glycosides. Part 1. New Synthesis of 1,2-trans O-Aryl Glycosides, via Tributyltin Phenoxides

Clerici, Francesca,Gelmi, Maria Luisa,Mottadelli, Sabrina

, p. 985 - 988 (2007/10/02)

A new method of glycosidation of phenols has been studied.The reaction of tributyltin phenoxides 2 with 1,2,3,4,6-penta-O-acetyl-D-hexopyranosides 3, 7 and 9, in the presence of tin tetrachloride is described.Glycosides 4, 8 and 10 have been isolated in g

Studies on glycosides. X. An alternative method for highly stereoselective synthesis of alkyl-β-D-glucopyranosides

Li,Cai,Cai

, p. 2121 - 2124 (2007/10/02)

An alternate method for the synthesis of alkyl-β-D-glucopyranosides using 2,3,4,6-tetra-O-acetyl-1-O-trifluoroacetyl-α-D-glucopyranose with alcohols or phenols in the presence of Lewis acid at low temperature was reported. β-anomers were the sole product

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