61308-51-8

Basic information

• Product Name: 3-(4-methylphenyl)-1,3-oxazinan-2-one
• CAS NO: 61308-51-8
• Molecular Formula: C₁₁H₁₃NO₂
• Molecular Weight: 191.2264
• Mol File: 61308-51-8.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 305.1°C at 760 mmHg
• Flash Point: 138.3°C
• Density: 1.155g/cm³
• Vapor Pressure: 0.000841mmHg at 25°C
• Refractive Index: 1.553
• CAS DataBase Reference: 3-(4-methylphenyl)-1,3-oxazinan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(4-methylphenyl)-1,3-oxazinan-2-one(61308-51-8)
• EPA Substance Registry System: 3-(4-methylphenyl)-1,3-oxazinan-2-one(61308-51-8)

Safety Data

• Hazardous Substances Data: 61308-51-8(Hazardous Substances Data)

Upstream product

• 124-38-9 carbon dioxide 
• 106-49-0 p-toluidine 
• 142-28-9 1,3-Dichloropropane 
• 17351-61-0 tetraethylammonium bicarbonate 
• 109-64-8 1,3-dibromo-propane 
• 503-30-0 trimethylene oxide 
• 622-58-2 p-Tolylisocyanate 
• 29425-64-7 p-tolyl-carbamic acid 3-bromo-propyl ester 

Relevant articles and documents

Synthesis of Oxazolidinones and Derivatives through Three-Component Fixation of Carbon Dioxide

An effective three-component fixation of atmospheric CO2 with readily available 1,2-dichloroethane and aromatic amine toward oxazolidinones catalyzed by in situ NHC was developed. The reaction occurred in good to excellent yields with good gene

The Cycloaddition of Heterocumulenes to Oxetanes in the Presence of Catalytic Amounts of Tetraphenylstibonium Iodide

The cycloadditions of carbon dioxide, isocyanates and carbodiimides to oxetanes proceeded in the presence of catalytic amounts of tetraphenylstibonium iodide (1) under mild conditions, affording the corresponding six-membered heterocycles; 1,3-dioxan-2-ones, 1,3-oxazin-2-ones and 1,3-oxazin-2-imines in good yields, respectively.Moreover, the cycloaddition of 2-phenyloxetane proceeded via predominant ring-cleavage at substituted site.

NOVEL USE OF ORGANOTIN HALIDE-BASE COMPLEX IN ORGANIC SYNTHESIS. CYCLOADDITION REACTION OF OXETANE WITH ISOCYANATES.

Cycloadditions of oxetanes with isocyanates were markedly accelerated by the complex of Bu2SnI2 and Ph3P=O which could be readily handled and hardly caused a trimerization of isocyanates, yielding oxazin-2-ones under neutral and mild reaction conditions.