61315-76-2Relevant academic research and scientific papers
Preparation of (S)-γ-cyclogeraniol by lipase-catalyzed transesterification and synthesis of (+)-trixagol and (+)-luffarin-P
Fujii, Mikio,Morimoto, Yosuke,Ono, Machiko,Akita, Hiroyuki
, p. 160 - 166 (2015/12/04)
Lipase-catalyzed kinetic resolution of γ-cyclogeraniol by Candida antarctica lipase B yielded 23% of enantiomerically pure (S)-γ-cyclogeraniol. (+)-trixagol and (+)-luffarin-P were synthesized from the obtained (S)-γ-cyclogeraniol, and the absolute config
A NEW SYNTHESIS OF Δ2-BUTENOLIDES VIA STEREOSELECTIVE FORMATION OF α,β-ETHYLENIC ESTERS
Larcheveque, M.,Legueut, Ch.,Debal, A.,Lallemand, J. Y.
, p. 1595 - 1598 (2007/10/02)
A new synthesis of Δ2-butenolides is described which involves stereoselective condensation of an α-silyl ester anion with an α-ketoacetal.
A Palladium-Catalyzed Stereospecific Substitution Reaction of Homoallylzincs with β-Bromo-Substituted α,β-Unsaturated Carbonyl Derivatives. A Highly Selective Synthesis of Mokupalide
Kobayashi, Makoto,Negishi, Ei-ichi
, p. 5223 - 5225 (2007/10/02)
Stereodefined homoallylzinc halides readily participate in a Pd-catalyzed stereospecific (>/= 98percent) substitution reaction with β-bromo-substituted α,β-unsaturated carbonyl derivatives, thereby providing a highly stereoselective and efficient route to butenolides and furans of terpenoid origin, such as mokupalide (1) and dendrolasin (2).
