613669-00-4Relevant academic research and scientific papers
Unexpected Syn Hydride Migration in the Non-aldol Aldol Reaction
Jung, Michael E.,Van Den Heuvel, Alexandra,Leach, Andrew G.,Houk
, p. 3375 - 3378 (2007/10/03)
(Equation Presented) Non-aldol aldol rearrangement of the epoxy silyl ether 13b afforded the expected anti methyl ketone 14, while the diastereomeric epoxy silyl ether 13a afforded the syn methyl ketone 8b via an unprecedented syn hydride migration. Calcu
