6137-06-0Relevant academic research and scientific papers
Specific features of thermal degradation of polypropylene in the presence of magnesium hydroxide
Koverzanova,Usachev,Shilkina,Lomakin,Gumargalieva,Zaikov
, p. 445 - 448 (2007/10/03)
Specific features of thermal oxidative degradation of polypropylene and its composite with Mg(OH)2 were studied by pyrolytic gas chromatography-mass spectrometry and thermal gravimetric analysis.
Copper-catalysed asymmetric conjugate addition of organometallic reagents to linear enones using thiourethane ligands
Bennett, Simon M.W.,Brown, Stephen M.,Muxworthy, James P.,Woodward, Simon
, p. 1767 - 1770 (2007/10/03)
In the presence of chiral thiourethane ligands [Cu(MeCN)4]BF4 forms active catalysts for the conjugate addition of MeMgBr, ZnEt2 and AlR3 (R = Me, Et) to non-3-en-2-one, hept-3-en-2-one, and 5-methylhex-3-en-2-one. Enantioselectivities of up to 51% are realised for these difficult substrates; for cyclohex-2-enone an e.e. of 42% is attained.
