61394-81-8Relevant academic research and scientific papers
Arylation and vinylation of activated carbons
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, (2008/06/13)
The present invention provides transition-metal-catalyst-based methods for the arylation and vinylation of activated methyl, methylene, and methine carbons with aryl halides, vinyl halides, and the like. The methods of the invention provide several improv
Highly active and selective catalysts for the formation of α-aryl ketones
Fox, Joseph M.,Huang, Xiaohua,Chieffi, Andre,Buchwald, Stephen L.
, p. 1360 - 1370 (2007/10/03)
Bulky, electron-rich phosphine ligands with a biphenyl backbone, when combined with Pd(OAc)2, give highly active catalysts for the α-arylation of ketones. The ligand 2-methyl-2'-dicyclohexylphosphinobiphenyl is particularly effective, and with
