6142-49-0

Basic information

• Product Name: cis-bicyclo<5.1.0>octan-2-ol
• CAS NO: 6142-49-0
• Molecular Weight: 126.199
• Mol File: 6142-49-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: cis-bicyclo<5.1.0>octan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: cis-bicyclo<5.1.0>octan-2-ol(6142-49-0)
• EPA Substance Registry System: cis-bicyclo<5.1.0>octan-2-ol(6142-49-0)

Safety Data

• Hazardous Substances Data: 6142-49-0(Hazardous Substances Data)

Upstream product

• 75-11-6 diiodomethane 
• 79605-67-7 2-cycloheptenol 
• 826-13-1 2-cycloheptenyl acetate 
• 92294-32-1 4-bromo-benzenesulfonic acid cyclooct-3c-enyl ester 
• 31022-91-0 exo-8,8-Dichlorobicyclo<5.1.0>octan-2-ol 

Relevant articles and documents

Samarium-Promoted Cyclopropanation of Allylic Alcohols

The use of samarium/mercury amalgam in conjunction with diiodomethane or chloroiodomethane to generate samarium carbenoids for the efficient cyclopropanation of allylic alcohols is discussed.These hydroxyl-directed cyclopropanations occur under mild conditions and allow a wide range of substitution about both the olefin and the carbinol carbon in allylic alcohol substrates.High yields and high diastereoselectivities are observed for many substrates.

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