6142-56-9

Upstream product

• 872164-43-7 N-(phenylthio)cyclohex-3-enecarboxamide 

Downstream Products

• 92673-58-0 N-Acetyl-2,4-trimethylen-pyrrolidon-(5) 
• 74403-58-0 N-benzoyl aza-6 bicyclo<3.2.1>octane 
• 74403-61-5 ((1S,2R,5R)-2-Hydroxy-6-aza-bicyclo[3.2.1]oct-6-yl)-phenyl-methanone 
• 74403-59-1 (1R,2S,5R)-6-Benzyl-2-hydroxy-6-aza-bicyclo[3.2.1]octan-7-one 
• 89764-12-5 (1S,2R,5R)-6-Benzyl-6-aza-bicyclo[3.2.1]octan-2-ol 
• 87091-39-2 6-<2-(3,4,5-trimethoxyphenyl)-2-ethoxyethyl>-6-azabicyclo<3.2.1>octan-7-one 
• 87091-36-9 6-<2-(3,4,5-trimethoxyphenyl)-2-hydroxyethyl>-6-azabicyclo<3.2.1>octan-7-one 
• 87091-35-8 6-(3,4,5-trimethoxyphenacyl)-6-azabicyclo<3.2.1>octan-7-one 
• 87091-37-0 6-(3,4,5-trimethoxyphenethyl)-6-azabicyclo<3.2.1>octan-7-one 
• 34584-03-7 N-benzyl aza-6 bicyclo<3.2.1>octanone-7 
• 89764-12-5 (1S,2R,5R)-6-Benzyl-6-aza-bicyclo[3.2.1]octan-2-ol 
• 74403-58-0 (S)-6-Aza-bicyclo[3.2.1]oct-6-yl-phenyl-methanone 

Relevant academic research and scientific papers

First examples of intramolecular addition of primary amidyl radicals to olefins

The first examples of intramolecular addition of primary amidyl radicals to olefins are described. Amidyl radicals were generated from N-(phenylthio)amides in refluxing benzene using a catalytic amount of 2,2′- azobis(isobutyronitrile) (5 mol%) and tributyltin hydride (sim;2.2 equiv.). The resulting yields of cyclic products ranged from 63% to 85%.