61455-15-0Relevant academic research and scientific papers
Thiadiaziridine 1,1-Dioxides: Synthesis and Chemistry
Timberlake, Jack W.,Alender, Jeff,Garner, Archie W.,Hodges, Melvin L.,Oezmeral, Cenan,et al.
, p. 2082 - 2089 (2007/10/02)
The synthesis and chemical reactions of a series of thiadiaziridine 1,1-dioxides (2) are described.The thermal stability is highly dependent on the R group and in one case (R = tert-octyl) is postulated that the thermolysis initially produces a diradical intermediate which can be trapped or further fragments to give a nitrene.A temperature-dependent NMR study on the coalescence of the diastereotopic α-methyl protons of 2b gives a ΔG = 20 kcal*mol-1.
