614717-89-4Relevant articles and documents
Hydrogen bonded supramolecular framework in inorganic-organic hybrid compound: Syntheses, crystal structure, thermal stability, and photoluminescent properties
Yan, Li,Li, Chuanbi,Fu, Jia,Sun, Mingzhe
, p. 814 - 818 (2014)
A novel compound [Mn(bip)2Cl2·4H2O] (1) [bip = 2-(4-bromophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline] has been synthesized by hydrothermal reactions and characterized by elemental analysis, thermogravimetric (TG) analysis, infrared spectrum (IR), XRD spectra (X-ray powder diffraction), and single-crystal X-ray diffraction. The title compound crystallizes in orthorhombic, space group pbcn with a = 1.4820, b = 0.8961, c = 2.8105 nm, β = 90°. Single-crystal X-ray diffraction reveals that compound 1 is zero-dimensional (0D) architecture, and the existence of hydrogen bonds and π-π interactions lead the 0D to 2D novel frameworks. Hydrogen bonds and π-π interactions are powerful interactions for directing supra-molecular architectures. TG analysis shows clear courses of weight loss, which corresponds to the decomposition of different ligands. The luminescent properties for the ligand bip and compound 1 are also discussed.
The synthesis and evaluation of the antitumor and antibacterial activity of two novel oxovanadium complexes
Cheng, Jianxin,Huang, Bin,Jiang, Guijjuan,Liao, Xiangwen,Wang, Jing,Wang, Jintao,Wang, Liqiang,Xiong, Yanshi
, p. 1016 - 1021 (2021/10/19)
Two novel oxovanadium(IV) complexes ([VO(hntdtsc)(BPIP)] and [VO(hntdtsc)(MOPIP)] (hntdtsc = 2-hydroxy-1-naphthaldehydethiosemicarbazone, BPIP = 2-(4-bromophenyl)-imidazo[4,5-f]-1,10-phenanthroline, MOPIP = 2-(4-methoxyphenyl)-imidazo[4,5-f]1,10-phenanthr
Synthesis method of arylimidazophenanthroline fluorescence dye, and recognition of metal ions
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Paragraph 0012, (2020/02/20)
The invention discloses a synthesis method of an arylimidazophenanthroline fluorescence dye, and recognition of metal ions. The synthesis method is a method for synthesizing arylimidazo[4,5-f]phenanthroline oxa-crown ether compounds from cheap and easily available 1,10-phenanthroline through a series of steps. Fluorescence properties of the arylimidazo[4,5-f]phenanthroline compounds are screened,the complexing property of the compounds and metal ions is verified through screening experiments of different metal ions and experiments of ion concentration and the like, and recognition of the metal ions Zn in tumor cells is achieved. The fluorescence probe has the following technical effects: 1, the compounds respectively have high selectivity to Zn Zn on wide metal ions; and 2, a fluorescence quenching molecular switch responding to Zn can be obtained in MCF-7 cells, and lays a great foundation for the application of the system in fields of biological recognition and the like.