61494-52-8

Basic information

• Product Name: 1-PYRENESULFONYL CHLORIDE
• Synonyms: 1-PYRENESULFONYL CHLORIDE;PYRENE 1-SULFONYL CHLORIDE
• CAS NO: 61494-52-8
• Molecular Formula: C₁₆H₉ClO₂S
• Molecular Weight: 300.76
• Mol File: 61494-52-8.mol
• Article Data: 12

Chemical Properties

• Boiling Point: 472 °C at 760 mmHg
• Flash Point: 239.3 °C
• Appearance: /
• Density: 1.514 g/cm³
• Vapor Pressure: 1.26E-08mmHg at 25°C
• Refractive Index: 1.805
• Storage Temp.: 2-8°C
• Solubility: Soluble in acetonitrile, chloroform, N,Ndimethylformamide, methanol, xylenes
• CAS DataBase Reference: 1-PYRENESULFONYL CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-PYRENESULFONYL CHLORIDE(61494-52-8)
• EPA Substance Registry System: 1-PYRENESULFONYL CHLORIDE(61494-52-8)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 3261 8/PG 2
• Hazardous Substances Data: 61494-52-8(Hazardous Substances Data)

Usage

General Description

1-Pyrenesulfonyl Chloride is a chemical compound with the molecular formula C16H9ClO2S. It is a photosensitive and moisture-sensitive yellow solid that is soluble in organic solvents. 1-PYRENESULFONYL CHLORIDE is commonly used as a building block in organic synthesis to create various other chemicals and pharmaceuticals. It is also utilized in the production of dyes, pesticides, and pharmaceuticals. 1-Pyrenesulfonyl Chloride is a hazardous chemical that should be handled with caution and proper safety measures, as it can cause irritation to the skin, eyes, and respiratory system upon contact.

InChI:InChI=1/C16H9ClO2S/c17-20(18,19)14-9-7-12-5-4-10-2-1-3-11-6-8-13(14)16(12)15(10)11/h1-9H

Upstream product

• 59323-54-5 sodium pyrene-1-sulfonate 
• 129-00-0 pyrene 
• 26651-23-0 pyrene-1-sulfonic acid 
• 1714-29-0 1-bromopyrene 

Downstream Products

• 123966-27-8 (4-chloro-benzyl)-dimethyl-[3-(pyrene-1-sulfonylamino)-propyl]-ammonium; chloride 

Relevant articles and documents

A facile method for detection of substituted salicylic acids using pyrenesulfonamide-terminated self-assembled monolayers on silicon oxide surfaces

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Monomolecular Layers of Pyrene as a Sensor to Dicarboxylic Acids

A new photoinduced luminescence film was prepared by immobilizing pyrene on a quartz plate surface via a flexible long spacer. The film displayed combined monomer and excimer emission of pyrene both in wet and dry states, and the excimer might be formed mainly by direct excitation of ground-state dimers and/or monomers in aggregates. Both the monomer emission and the eximer emission were sensitized by introduction of some dicarboxylic acids. This phenomenon was ascribed to the insertion of dicarboxylic acids into the space between the neighboring spacers. In contrast, introduction of monocarboxylic acids, e.g., formic acid and acetic acid, had little influence on the emission of the functional film. Response of the film to dicarboxylic acids was reversible, and the film was stable within a number of months if it was properly preserved. These characteristics guaranteed the film as a potential sensing material for common dicarboxylic acids.

Four different emissions from a Pt(Bodipy)(PEt3)2(S-Pyrene) dyad

The Pt(bodipy)-(mercaptopyrene) dyad BPtSPyr shows four different emissions: intense near-infrared phosphorescence (Φph up to 15%) from a charge-transfer state pyrS+-Pt-BDP-, additional fluorescence and phosphorescence emissions from the 1ππ? and 3ππ? states of the bodipy ligand at r.t., and phosphorescence from the pyrene 3ππ? and the bodipy 3ππ? states in a glassy matrix at 77 K.

NOVEL COMPOUND AND CIANIDE ION DETECTING CHEMICAL SENSOR INCLUDING THE COMPOUND

In a novel compound and a chemical sensor including the same, the novel compound is represented by the following chemical formula 1. [Chemical formula 1] L1 and L2, independently, indicate *-(CH2)n-*; (Herein, n is an integer of 2-5.) and A- indicates Br-, Cl-, PF6- or NO3-.COPYRIGHT KIPO 2015