615256-61-6Relevant academic research and scientific papers
Diastereoselective Johnson-Corey-Chaykovsky trifluoroethylidenation
Duan, Yaya,Zhou, Bin,Lin, Jin-Hong,Xiao, Ji-Chang
, p. 13127 - 13130 (2015)
(2,2,2-Trifluoroethyl)diphenylsulfonium triflate was found to be an efficient ylide reagent for the Johnson-Corey-Chaykovsky reaction to afford trifluoromethyl epoxides, cyclopropanes and aziridines. Interestingly, excellent but different diastereoselectivity was observed for these transformations. Both trifluoromethyl epoxides and cyclopropanes were obtained with trans-selectivity, whereas aziridines were obtained with cis-selectivity.
Enantioselective borodeuteride reduction of aldimines catalyzed by cobalt complexes: Preparation of optically active deuterated primary amines
Miyazaki, Daichi,Nomura, Kohei,Yamashita, Tatsuya,Iwakura, Izumi,Ikeno, Taketo,Yamada, Tohru
, p. 3555 - 3558 (2007/10/03)
[Equation presented] The enantioselective borodeuteride reduction catalyzed by optically active β-ketoiminato cobalt complexes was applied to N-(di(o-tolyl)phosphinyl)-aldimines to afford the corresponding optically active deuterated primary amines in hig
