615266-92-7Relevant academic research and scientific papers
Abnormal and regioselective Wacker oxidation of 1,5-dienes
Ho, Tse-Lok,Chang, May Hua,Chen, Chuo
, p. 6955 - 6957 (2003)
The presence of an additional double bond can change the regioselectivity of the Wacker oxidation of a 1-alkene moiety to give the aldehyde product.
Synthesis of C-13 oxidised cuparene and herbertane sesquiterpenes via a Paternò-Büchi photocyclisation-oxetane fragmentation strategy: Total synthesis of 1,13-herbertenediol
Boxall, Richard J.,Ferris, Leigh,Grainger, Richard S.
, p. 2379 - 2381 (2007/10/03)
The intramolecular Paternò-Büchi reaction of 5-aryl-4,4-dimethyl-hex-5-enals has been used to assemble the hindered cyclopentane skeleton of the cuparene and herbertane sesquiterpenes. Regioselective carbon-oxygen bond cleavage in the resulting oxetane is
