615268-34-3

Upstream product

• 56964-65-9 methyl 2-benzyl-3-phenylpropanoate 
• 618-68-8 2-benzyl-3-phenylpropanoic acid 
• 615268-33-2 ethyl 2,2-dibenzyl-pent-4-enoate 

Downstream Products

• 615268-42-3 (4R)-N-benzyl-N-(tert-butyloxycarbonyl)-2,2-dibenzyl-4-diphenylphosphatoxy-5-methyl-5-nitrohexylamine 
• 615268-26-3 (4R)-N-benzyl-2,2-dibenzyl-4-diphenylphosphatoxy-5-methyl-5-nitrohexylamine 
• 615268-41-2 (4R)-N-benzyl-N-(tert-butyloxycarbonyl)-2,2-dibenzyl-4-hydroxy-5-methyl-5-nitrohexylamine 
• 615268-39-8 N-benzyl-N-(tert-butyloxycarbonyl)-2,2-dibenzyl-4-hydroxy-5-methyl-5-nitro-hexylamine 
• 904325-38-8 N-benzyl-2,2-dibenzyl-5-methyl-5-nitro-4-oxo-hexylamine 
• 615268-37-6 5-[N-benzyl-N-(tert-butyloxycarbonyl)]amino-4,4-dibenzyl-pent-1-ene 
• 615268-38-7 4-[N-benzyl-N-(tert-butyloxycarbonyl)]amino-3,3-dibenzyl-butanal 
• 615268-36-5 5-benzylamino-4,4-dibenzyl-pent-1-ene 

Relevant academic research and scientific papers

Asymmetric Intramolecular Hydroalkoxylation of Unactivated Alkenes Catalyzed by Chiral N-Triflyl Phosphoramide and TiCl4?

By using a combination of a chiral N-triflyl phosphoramide and TiCl4 as the catalyst, a new process for asymmetric intramolecular hydroalkoxylation of unactivated alkenes was developed, producing various chiral tetrahydrofuran derivatives in 51%—99% yields with 30%—71% ee's.

Enantioselective alkene radical cations reactions

The reaction of enantiomerically enriched 2-methyl-2-nitro-3-(diphenylphosphatoxy)alkyl radicals with tributyltin hydride and AIBN in benzene at reflux results in the formation of alkene radical cation/anion pairs, which are trapped intramolecularly by am

Enantioselective cyclization of alkene radical cations

(Matrix Presented) Enantiomerically enriched β-(diphenylphosphatoxy) nitroalkanes undergo radical ionic fragmentation, induced by tributyltin hydride and AIBN in benzene at reflux, to give alkene radical cations in contact radical ion pairs. These contact