615553-87-2Relevant academic research and scientific papers
Cationic benzyl zirconium heteroscorpionates: Synthesis and characterization of a novel ethylene polymerisation catalyst showing an unusual temperature dependent polymerisation mechanism
Milione, Stefano,Montefusco, Cosimo,Cuenca, Tomas,Grassi, Alfonso
, p. 1176 - 1177 (2003)
The reaction of (bpzmp)Zr(CH2Ph)3 with B(C6F5)3 produces the active ethylene polymerisation catalyst [(bpzmp)Zr(CH2Ph)2] +[PhCH2B(C6F5) 3]- which showed a temperature dependent polymerisation mechanism identified by variable temperature 1H NMR analysis of the catalyst solution.
