615562-56-6Relevant academic research and scientific papers
Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne- and 1-allene-vinylcyclopropanes
Jiao, Lei,Lin, Mu,Yu, Zhi-Xiang
supporting information; experimental part, p. 1059 - 1061 (2010/06/18)
New Rh(i)-catalyzed intramolecular [3 + 2] cycloaddition reactions of 1-ene-, 1-yne and 1-allene-vinylcyclopropanes have been developed, affording an efficient and versatile synthesis of cyclopentane- and cyclopentene-embedded bicyclic structures.
Rhodium-Catalyzed Asymmetric [5+2] Cycloaddition of Alkyne- Vinylcyclopropanes
Shintani, Ryo,Nakatsu, Hiroki,Takatsu, Keishi,Hayashi, Tamio
supporting information; experimental part, p. 8692 - 8694 (2010/03/24)
The development of such an asymmetric catalysis by the use of a rhodium complex coordinated with chiral phosphoramidite ligand, achieving very high enantiomeric excesses has been reported. Transition-metal-catalyzed cycloaddition of vinylcyclopropanes wit
A mechanistic dichotomy in ruthenium-catalyzed propargyl alcohol reactivity: A novel hydrative diyne cyclization
Trost, Barry M.,Rudd, Michael T.
, p. 11516 - 11517 (2007/10/03)
The cycloisomerization of diyne-ols catalyzed by [CpRu(CH3CN)3]PF6 to 2-vinyl-1-acylcycloalkenes proceeds via a ruthenacyclopentadiene involving initial ionization of the tertiary or secondary alcohol, followed by readditi
