615574-93-1Relevant academic research and scientific papers
The first enzymatic resolution of quaternary α-acetoxy α-substituted cyclic ketones
Tanyeli, Cihangir,Akhmedov, Idris M.,Iyiguen, Cigdem
, p. 1125 - 1128 (2006)
The enantioselective resolution of quaternary α-acetoxy α-substituted indanone and 1-tetralone derivatives was performed with commercially available enzyme CRL in pH = 8.0 phosphate buffer. Various parameters that would affect the enantoselectivities were tested, and the optimal enzymatic resolution condition was found to afford the enantiomerically enriched quaternary acetoxylated substrates with high ees (varied between 81% and 85%).
Manganese(III) acetate based oxidation of substituted α′-position on cyclic α,β-unsaturated ketones
Tanyeli, Cihangir,Iyigün, ?igdem
, p. 7135 - 7139 (2007/10/03)
Selective oxidation of the tertiary α′-position on various 2-cyclopentenone, 2-cyclohexenone and aromatic ketone derivatives with manganese(III) acetate is described.
