6159-95-1

Basic information

• Product Name: 3-Phenyl-1.3-butadien-2-carbonsaeure-ethylester
• CAS NO: 6159-95-1
• Molecular Weight: 202.253
• Mol File: 6159-95-1.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 3-Phenyl-1.3-butadien-2-carbonsaeure-ethylester(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Phenyl-1.3-butadien-2-carbonsaeure-ethylester(6159-95-1)
• EPA Substance Registry System: 3-Phenyl-1.3-butadien-2-carbonsaeure-ethylester(6159-95-1)

Safety Data

• Hazardous Substances Data: 6159-95-1(Hazardous Substances Data)

Upstream product

• 100641-07-4 1-ethoxy-3-trimrthylsilyl-prop-1-yne 
• 532-27-4 1-chloroacetophenone 

Relevant articles and documents

Facile regio- and stereoselective metal-free synthesis of all-carbon tetrasubstituted alkenes bearing a C(sp3)-F unit via dehydroxyfluorination of morita-baylis-hillman (MBH) adducts

Highly E-selective all-carbon tetrasubstituted alkenes with a C(sp 3)-F unit have been synthesized through a dehydroxyfluorination of Morita-Baylis-Hillman (MBH) adducts which can be readily prepared from α,β-unsaturated carbonyl compounds and α-keto esters. A variety of subsequent transformations afforded monofluoromethyl substituted heterocycles in high yields.

REACTION DE CYCLOADDITION ENTRE L'ETHOXY-1 TRIMETHYSILYL-3 PROPYNE-1 ET LES CETONES α-HALOGENEES: SYNTHESE EN UNE ETAPE D'ESTERS DIENIQUES CONJUGUES

In the presence of titanium tetrachloride, 1-ethoxy-3-trimethylsilyl-1-propyne easily reacts with many α-haloketones to lead to dienic conjugated esters; an α-ethylenic lactone may be obtained when the halogen is on a tertiary carbon atom.