61593-25-7Relevant academic research and scientific papers
ELECTROPHILICALLY CATALYZED SPLITTING OF DIMETHOXYAMINE TO METHOXYNITRENIUM ION AND ITS REACTIONS
Rudchenko, V. F.,Ignatov, S. M.,Chervin, I. I.,Aliev, A. E.,Kostyanovskii, R. G.
, p. 1249 - 1253 (2007/10/02)
The electrophilically catalyzed splitting of the N-O bond of dimethoxyamine results in the formation of methoxynitrenium ion, which in reaction with nucleophiles exhibits properties of an ambidentate cation - it methylates rigid nucleophiles and epiminates olefins.The stereospecificity of the addition of the nitrenium ion to cis-2-butene indicates its existence in a singlet electronic ground state.
