616206-02-1

Basic information

• Product Name: 2-((S)-3-Isopropyl-1-methyl-cyclopent-2-enyl)-1-(2-methoxy-6-methoxymethoxy-4-methyl-phenyl)-ethanone
• CAS NO: 616206-02-1
• Molecular Weight: 346.467
• Mol File: 616206-02-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-((S)-3-Isopropyl-1-methyl-cyclopent-2-enyl)-1-(2-methoxy-6-methoxymethoxy-4-methyl-phenyl)-ethanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-((S)-3-Isopropyl-1-methyl-cyclopent-2-enyl)-1-(2-methoxy-6-methoxymethoxy-4-methyl-phenyl)-ethanone(616206-02-1)
• EPA Substance Registry System: 2-((S)-3-Isopropyl-1-methyl-cyclopent-2-enyl)-1-(2-methoxy-6-methoxymethoxy-4-methyl-phenyl)-ethanone(616206-02-1)

Safety Data

• Hazardous Substances Data: 616206-02-1(Hazardous Substances Data)

Upstream product

• 80393-02-8 1-oxymethylenemethoxy-3-methoxy-5-methylbenzene 
• 616206-00-9 ((S)-3-Isopropyl-1-methyl-cyclopent-2-enyl)-acetaldehyde 
• 616205-97-1 2-((1S,3S)-3-Isopropyl-1-methyl-2-methylene-cyclopentylmethyl)-[1,3]dioxolane 
• 616206-19-0 (2S,5S)-2-[1,3]Dioxolan-2-ylmethyl-5-isopropyl-2-methyl-cyclopentanol 
• 616205-98-2 (2S,5S)-2-[1,3]Dioxolan-2-ylmethyl-5-isopropyl-2-methyl-cyclopentanone 
• 616205-99-3 2-((S)-3-Isopropyl-1-methyl-cyclopent-2-enylmethyl)-[1,3]dioxolane 

Downstream Products

• 616206-05-4 (S)-trifluoromethanesulfonic acid 2-[2-(3-isopropyl-1-methylcyclopent-2-enyl)acetyl]-3-methoxy-5-methylphenyl ester 

Relevant articles and documents

Enantiospecific total synthesis of 6-epi-(-)-hamigeran B. Intramolecular Heck reaction in a sterically constrained environment

An enantiospecific approach, emanating from the abundantly available chiron R-(+)-limonene, to the biologically potent, novel marine natural products, the hamigerans has been developed in which an intramolecular Heck coupling between aryl triflates and an alkene serves as the pivotal step. Following this strategy, a synthesis of (-)-6-epi-hamigeran B has been accomplished.