616223-76-8

Basic information

• Product Name: 8-hydroxynonyl acetate
• Synonyms: 8-hydroxynonyl acetate
• CAS NO: 616223-76-8
• Molecular Weight: 202.294
• Mol File: 616223-76-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 8-hydroxynonyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 8-hydroxynonyl acetate(616223-76-8)
• EPA Substance Registry System: 8-hydroxynonyl acetate(616223-76-8)

Safety Data

• Hazardous Substances Data: 616223-76-8(Hazardous Substances Data)

Upstream product

• 76238-22-7 cis-non-6-en-1-yl acetate 

Relevant articles and documents

Tandem isomerization/hydroformylation/hydrogenation of internal alkenes to n-alcohols using Rh/Ru dual-or ternary-catalyst systems

A one-pot three-step reaction, isomerization/hydroformylation/hydrogenation of internal alkenes to n-alcohols, was accomplished by employing a Rh/Ru dual-catalyst system. By using a combination of Rh(acac)(CO)2/ bisphosphite and Shvo's catalyst, (Z)-2-tridecene was converted to 1-tetradecanol in 83% yield with high normal/iso selectivity (n/i = 12). The method was applicable to other internal alkenes, including functionalized alkenes, such as an alkenol and an alkenoate. Furthermore, addition of a third component, Ru3(CO)12, effectively improved the n/i ratio in the tandem isomerization/hydroformylation/hydrogenation of methyl oleate (from n/i = 1.9 to 4.4). Control experiments revealed that the isomerization was mediated by both Rh and Ru and that the coexistence of Rh and Ru was essential for hydrogenation of aldehyde under H2/CO.