61631-71-8Relevant academic research and scientific papers
Rh-Catalyzed Conversion of 3-Diazoindolin-2-imines to 5H-Pyrazino[2,3-b]indoles with Photoluminescent Properties
Ding, Hualong,Wang, Zaibin,Bai, Songlin,Lu, Ping,Wang, Yanguang
supporting information, p. 6514 - 6517 (2017/12/26)
A rhodium-catalyzed reaction between 3-diazoindolin-2-imines and 2H-azirines, followed by treatment with a base, furnishes 5H-pyrazino[2,3-b]indoles in excellent yields. A number of functional groups tolerate the reaction conditions, and the resulting 5H-
Ruthenium-Catalyzed C-C Bond Cleavage of 2H-Azirines: A Formal [3+2+2] Cycloaddition to Fused Azepine Skeletons
Li, Tengfei,Xu, Fen,Li, Xincheng,Wang, Chunxiang,Wan, Boshun
supporting information, p. 2861 - 2865 (2016/02/27)
2H-azirines can serve as three-atom synthons by C-C bond cleavage, however, it involves a high energy barrier under thermal conditions (>50.0 kcal mol-1). Reported is a ruthenium-catalyzed [3+2+2] cycloaddition reaction of 2H-azirines with diyn
Ruthenium-Catalyzed [3 + 2] Cycloaddition of 2H-Azirines with Alkynes: Access to Polysubstituted Pyrroles
Li, Tengfei,Yan, Hao,Li, Xincheng,Wang, Chunxiang,Wan, Boshun
, p. 12031 - 12037 (2016/12/09)
A ruthenium-catalyzed intermolecular [3 + 2] cycloaddition of 2H-azirines and activated alkynes is reported, which provides polysubstituted pyrroles in moderate to good yields. This approach features a C-N bond cleavage of 2H-azirines by a ruthenium catal
