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9-Oxabicyclo[3.3.1]non-3-en-2-ol, exo- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

61686-85-9

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61686-85-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 61686-85-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,1,6,8 and 6 respectively; the second part has 2 digits, 8 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 61686-85:
(7*6)+(6*1)+(5*6)+(4*8)+(3*6)+(2*8)+(1*5)=149
149 % 10 = 9
So 61686-85-9 is a valid CAS Registry Number.

61686-85-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 9-oxabicyclo<3.3.1>non-3-en-exo-2-ol

1.2 Other means of identification

Product number -
Other names 9-oxabicyclo[3.3.1]non-3-en-exo-2-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:61686-85-9 SDS

61686-85-9Downstream Products

61686-85-9Relevant academic research and scientific papers

Direct Epoxy Alcohol Synthesis from Cyclic Olefins Using O2 and VO(acac)2-AIBN Catalyst System

Kaneda, Kiyotomi,Jitsukawa, Koichiro,Itoh, Takashi,Teranishi, Shiichiro

, p. 3004 - 3009 (2007/10/02)

The vanadium-catalyzed oxidation of cyclic olefins with molecular oxygen is examined.The VO(acac)2-AIBN system is an efficient catalyst for epoxy alcohol synthesis.Chloro hydrocarbons such as 1,2-dichloroethane and 1,1,2-trichloroethane are suitable solvents for the epoxidation reaction.Cyclohexene (1), methylcyclohexene (2), and cyclododecene (5) give the corresponding epoxy alcohols in good yields; in the case of 2 with VO(acac)2-AIBN system, the selectivity to epoxy alcohol reaches over 70percent. 1,4-Cyclooctadiene (7) is oxidized to give 9-oxabicyclonon-3-en-exo-2-ol (6a) via the rearrangement of cis-2,3-epoxycyclooct-4-en-1-ol.Exceptional is cyclooctene (4), which gives exclusively cyclooctene oxide (4b).

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