61699-43-2

Upstream product

• 78-27-3 1-Ethynylcyclohexan-1-ol 
• 616-38-6 carbonic acid dimethyl ester 
• 79-22-1 methyl chloroformate 

Downstream Products

• 185536-18-9 2-(2-cyclohexylidenevinyl)-1-methylindole 
• 1094602-80-8 1,1-bis(methoxycarbonyl)-2-(5',5'-pentamethylene-1',3',4'-pentatrien-2'-yl)cyclopropane 
• 1094602-77-3 1,1-bis(methoxycarbonyl)-2-benzyl-2-(5',5'-pentamethylene-1',3',4'-pentatrien-2'-yl)cyclopropane 
• 1225232-83-6 2-isopropyl-3-(methoxycarbonyl)-5-(5,5-pentamethylene-1,3,4-pentatrien-2-yl)-4,5-dihydrofuran 
• 1225232-90-5 5-benzyl-2-isopropyl-3-(methoxycarbonyl)-5-(5,5-pentamethylene-1,3,4-pentatrien-2-yl)-4,5-dihydrofuran 
• 1225232-81-4 3-(ethoxycarbonyl)-2-methyl-5-(5,5-pentamethylene-1,3,4-pentatrien-2-yl)-4,5-dihydrofuran 
• 1284293-66-8 (Z)-N-benzyl 4-(3',3'-pentamethylenepropa-1',2'-dienyl)-5,5-dimethylfuran-2(5H)-imine 
• 1284293-75-9 (Z)-N-benzyl 4-(3',3'-pentamethylenepropa-1',2'-dienyl)-3,5,5-trimethylfuran-2(5H)-imine 
• 1446452-01-2 C₁₁H₁₆O₃ 
• 1446451-72-4 C₁₄H₂₄O₃Si 
• 1446451-71-3 C₁₄H₂₄O₃Si 
• 13487-14-4 <2-Methoxy-ethyl>-cyclohexyl-keton 
• 5240-36-8 1-ethynyl-1-methoxy-cyclohexane 
• 1609456-39-4 2-(2-cyclohexylidenevinyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant academic research and scientific papers

Gold(I)-catalyzed decarboxylation of propargyl carbonates: Reactivity reversal of the gold catalyst from π-Lewis acidity to σ-Lewis acidity

A cationic gold(I)-catalyzed decarboxylative etherification of propargyl carbonates to selectively produce propargyl ethers is reported. In the reaction the gold(I) catalyst shows a distinct σ-Lewis acidity rather than the commonly observed π-Lewis acidity, and thus catalyzes the decarboxylation of a variety of propargyl carbonates to give the corresponding propargyl ethers with high selectivity. This reaction represents a rare example of the tunable reactivity of cationic gold(I) complexes between σ-Lewis acidity and π-Lewis acidity.

Ester manufacturing method (by machine translation)

PROBLEM TO BE SOLVED: To produce an ester compound by transesterification using an inexpensive and low toxic inorganic compound. SOLUTION: Transesterification of an ester compound and an alcohol compound is carried out under the presence of lanthanum nitrate (for example, lanthanum nitrate hexahydrate) and a phosphine compound (for example, tri-n-octylphosphine), thereby obtaining the ester product. For example, transesterification of dimethyl carbonate and benzyl alcohol is carried out under the presence of 1 mol% of lanthanum nitrate hexahydrate, and 2 mol% of tri-n-octylphosphine, thereby obtaining benzyl methylcarbonate at a yield of >99%. COPYRIGHT: (C)2012,JPO&INPIT

Copper-catalyzed regiodivergent silacarboxylation of allenes with carbon dioxide and a silylborane

A regiodivergent silacarboxylation of allenes under a CO2 atmosphere with PhMe2Si-B(pin) as a silicon source in the presence of a copper catalyst at 70 °C has been developed. The regioselectivity of the reaction is successfully rever

In situ generated "lanthanum(iii) nitrate alkoxide" as a highly active and nearly neutral transesterification catalyst

In situ generated lanthanum(iii) nitrate alkoxide is a highly active and nearly neutral transesterification catalyst, which can promote non-epimerized transesterification of α-substituted chiral carboxylic esters under reflux conditions.

Lanthanum(III) isopropoxide catalyzed chemoselective transesterification of dimethyl carbonate and methyl carbamates

A practical transesterification of less reactive dimethyl carbonate and much less reactive methyl carbamates with primary (1°), secondary (2°), and tertiary (3°) alcohols was established with the use of a lanthanum(III) complex, which was prepared in situ from lanthanum (III) isopropoxide (3 mol %) and 2-(2-methoxyethoxy)ethanol (6 mol %). In particular, corresponding carbonates and carbamates obtained were of synthetic utility from the viewpoint of the selective protection and/or deprotection of 1°-, 2°-, and 3°-alcohols.

Cycloalkyl carbonates

Carbonic acid esters of the formula STR1 wherein R1 is a member having from 8 to 12 carbon atoms selected from the group consisting of alkylcyclohexyl, alkenylcyclohexyl, alkynylcyclohexyl and cycloalkyl, and R2 is a member selected from the group consisting of alkyl having from 1 to 5 carbon atoms, alkenyl having from 2 to 5 carbon atoms and alkynyl having from 2 to 5 carbon atoms, which compounds have pleasing and persistent scents, as well as processes for producing them and perfume compositions containing them.