61775-35-7Relevant academic research and scientific papers
Esterase-Activated Perthiocarbonate Persulfide Donors Provide Insights into Persulfide Persistence and Stability
Cerda, Matthew M.,Fosnacht, Kaylin G.,Mullen, Emma J.,Pigg, Hannah C.,Pluth, Michael D.
, (2022/01/28)
Persulfides (RSSH) are important reactive sulfur species (RSS) that are intertwined with the biological functions of hydrogen sulfide (H2S). The direct study of persulfides is difficult, however, due to their both nucleophilic and electrophilic
Triphenylphosphine Decomposition of Sulfenyl Thiocarbonates
Harpp, David N.,Granata, Alessandro
, p. 271 - 273 (2007/10/02)
Several sulfenyl thiocarbonates (RSSCO2CH3) have been decomposed with triphenylphosphine.In the case of R = alkyl, desulfurization takes place to give the S-alkyl thiocarbonate while in the case of R = aryl, a phosphonium salt is likely formed which on chromatographic workup on silica gel is converted to a thiol and triphenylphosphine oxide and sulfide.A mechanistic interpretation is offered.
