61784-07-4

Upstream product

• 213594-46-8 1,6-Anhydro-2-O-benzyl-4-benzylamino-4-deoxy-β-D-glucopyranose 
• 145240-53-5 1,6-Anhydro-4-azido-2-O-benzyl-4-deoxy-β-D-glucopyranose 

Relevant academic research and scientific papers

Preparation of diamino pseudodisaccharide derivatives from 1,6-anhydro-β-d-hexopyranoses via aziridine-ring cleavage

Twelve positional isomers of diamino pseudodisaccharide derivatives with gluco-gluco configuration have been prepared using aziridine-ring cleavage of epimino derivatives of 1,6-anhydro-β-d-hexopyranoses of the d-allo, d-manno, and d-galacto configuration

Selective N-debenzylation of benzylamino derivatives of 1,6-anhydro-β-D-hexopyranoses

(matrix presented) When the series of 2-, 3-, and 4-(benzylamino)-2-, 3-, and 4-deoxy derivatives of 1,6-anhydro-β-D-hexopyranoses in the D-gluco, D-lyxo, and D-arabino configurations were reacted with diisopropyl azodicarboxylate, N-benzyl groups were selectively cleaved in the presence of O-benzyl groups. The yields ranged from 51 to 97percent. The debenzylation of some aliphatic benzylamines is also discussed.