61794-43-2

Upstream product

• 651-80-9 1,2,4,5-tetrafluoro-3-(trifluoromethyl)benzene 
• 1868-85-5 (2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)hydrazine 
• 591-50-4 iodobenzene 
• 1227710-53-3 [bis(trifluoroacetoxy)iodo]-2,3,5,6-tetrafluoro-4-trifluoromethyl-benzene 

Downstream Products

• 137832-25-8 tribromogermylheptafluoro-4-methylbenzene 
• 1227710-53-3 [bis(trifluoroacetoxy)iodo]-2,3,5,6-tetrafluoro-4-trifluoromethyl-benzene 
• 1315381-38-4 C₃₂F₂₂ 
• 4526-07-2 1,4-bis(trimethylsilyl)-1,3-butadiyne 
• 61794-55-6 1.4-Bis-(4'-trifluormethyltetrafluorphenyl)butadiin 
• 61794-56-7 4-Trifluormethyltetrafluorphenylacetylen 
• 122571-42-0 trimethyl(2,3,5,6-tetrafluoro-4-(trifluoromethyl)phenyl)silane 
• 61794-47-6 1-(4-trifluoromethyl-2,3,5,6-tetrafluorophenyl)-1-propyn-3-ol 

Relevant academic research and scientific papers

A versatile and highly reactive polyfluorinated hypervalent iodine (III) compound

(Figure Presented) Hyper-reactive: A highly reactive, fully fluorinated hypervalent iodine reagent (see formula) mediates new transformations (e.g. the one-pot conversion of sulfides to sulfoximines) and serves as a stoichiometric oxidant in well-established reactions (e.g. C-C bond cleavage and the conversion of alcohols into aldehydes).

Fluoro-substituted phenyleneethynylenes: Acetylenic n-type organic semiconductors

Fluoro-substituted phenyleneethynylenes are synthesized by Sonogashira coupling and acetylide-nucleophilic substitution of fluorobenzenes. Fluoro-substitution of benzenes enables deep LUMO potential, and CF 3-substitution provides high electron

REACTIONS OF POLYFLUOROARYL BROMIDES AND IODIDES WITH C-, Si-, Ge-, Sn- AND Pb-ELECTROPHILES AND TRIS(DIALKYLAMINO)PHOSPHINES

The reactions of polyfluoroaryl bromides ArFBr or iodides ArFI with P(NR'2)3 and R3MX (R = alkyl; M = Si, Ge, Sn and Pb; X = Cl, Br) led to the formation of ArFMR3.The reactions of C6F5Br with P(NEt2)3 and C-electrophiles (CH3I, C6F5CF3 and (CF3)2C=CFC2F5) gave the products of pentafluorophenylation of these substrates.

C-I STRETCHING VIBRATIONS IN IODOBENZENES

Comparison of the calculated and experimental IR and Raman spectra of a series of iodobenzenes showed that the C-I stretching vibrations for these compounds correspond to a very highly polarized Raman band 150 - 270 cm-1 (ρ = 0.1).The position of this band depends on the mass of the para substituent and relative position of the fluorine and iodine atoms in the molecule.The UV absorption spectral data indicate an interaction of the iodine atom and para substituents through the ?-system.Opposite substituent effects on the change in intensity of the B-band in the UV spectra of iodobenzenes and tetrafluoroiodobenzenes were noted.