61826-75-3

Upstream product

• 108-24-7 acetic anhydride 
• 542-92-7 cyclopenta-1,3-diene 

Downstream Products

• 60410-16-4 (1R,4S)-4-hydroxy-2-cyclopentene-1-yl acetate 
• 60410-17-5 (1R,4R)-(+)-4-Hydroxy-2-cyclopentenyl acetate 
• 54664-61-8 cis-1,4-diacetoxy-2-cyclopentene 
• 60176-77-4 (1S,4R)-4-hydroxy-2-cyclopentenyl acetate 
• 239808-42-5 1-[(1R,2S,3R,4S)-2,3-bis[(tert-butyldimethylsilyl)oxy]-4-[N-(tert-butyldiphenylsilyl)oxyamino]cyclopent-1-yl]uracil 
• 239808-43-6 1-[(1R,2S,3R,4S)-2,3-bis[(tert-butyldimethylsilyl)oxy]-4-[N-(tert-butyldiphenylsilyl)oxyamino]cyclopent-1-yl]cytosine 
• 239808-22-1 N₃-benzoyl-1-[(1R,4S)-4-[(tert-butyldiphenylsilyl)oxy]-2-cyclopenten-1-yl]thymine 
• 239808-40-3 1-[(1R,2S,3R,4S)-4-[N-(tert-butyldiphenylsilyl)oxyamino]-2,3-dihydroxycyclopent-1-yl]uracil 
• 239808-23-2 N₃-benzoyl-1-[(1R,4S)-4-[(tert-butyldiphenylsilyl)oxy]-2-cyclopenten-1-yl]uracil 
• 239808-36-7 1-[(1S,4R)-4-[N-(tert-butyldiphenylsilyl)oxyamino]cyclopent-1-yl]thymine 
• 239808-34-5 1-[(1R,4S)-4-[N-(tert-butyldiphenylsilyl)oxyamino]-2-cyclopenten-1-yl]thymine 
• 239808-37-8 1-[(1S,4R)-4-[N-(tert-butyldiphenylsilyl)oxyamino]cyclopent-1-yl]uracil 
• 239808-35-6 1-[(1R,4S)-4-[N-(tert-butyldiphenylsilyl)oxyamino]-2-cyclopenten-1-yl]uracil 
• 239808-28-7 N₃-benzoyl-1-[(1R,4S)-4-(N-benzyloxyamino)-2-cyclopenten-1-yl]thymine 

Relevant academic research and scientific papers

Liquid-phase 1,4-Diacetoxylation of Conjugated Dienes with Tellurium(IV) Oxide and Alkali Metal Halides

Oxidation of buta-1,3-diene, isoprene, and 2,3-dimethylbuta-1,3-diene with tellurium(IV) oxide and lithium bromide in acetic acid affords an isomeric mixture of the corresponding diacetoxyalkenes (1,2- and 1,4-addition products).The product yield and selectivity for 1,4-isomers are high when an excess of LiBr is employed (LiBr/TeO2 = 5-10).The reaction also proceeds in the presence of NaBr, KBr, LiCl, HBr, or I2 in the place of LiBr, but both the selectivity for 1,4-isomers and the product yield are lower.The reaction hardly occurs using LiF, LiI, NaCl, Br2, and NH4Br as a halogen source.The reaction proceeds catalytically with respect to TeO2 to some extent when a re-oxidant such as H2O2 or t-BuOOH is used.In the cases of 2,5-dimethylhexa-2,4-diene, cyclopenta-1,3-diene, cyclohexa-1,3-diene, and cyclo-octa-1,3-diene the results are unsatisfactory in either the product yield or the selectivity for 1,4-isomers.Halogeno- and/or acetoxy-telluriation of a diene followed by acetolysis of the produced C-X (X = halogen) and C-Te bonds are proposed as one of the possible reaction pathways.