61841-48-3Relevant academic research and scientific papers
Control of the orientation and photoinduced phase transitions of macrocyclic azobenzene
Uchida, Emi,Sakaki, Kouji,Nakamura, Yumiko,Azumi, Reiko,Hirai, Yuki,Akiyama, Haruhisa,Yoshida, Masaru,Norikane, Yasuo
, p. 17391 - 17397 (2013)
Photoinduced phase transitions caused by photochromic reactions bring about a change in the state of matter at constant temperature. Herein, we report the photoinduced phase transitions of crystals of a photoresponsive macrocyclic compound bearing two azobenzene groups (1) at room temperature on irradiation with UV (365 nm) and visible (436 nm) light. The trans/trans isomer undergoes photoinduced phase transitions (crystal-isotropic phase-crystal) on UV light irradiation. The photochemically generated crystal exhibited reversible phase transitions between the crystal and the mesophase on UV and visible light irradiation. The molecular order of the randomly oriented crystals could be increased by irradiating with linearly polarized visible light, and the value of the order parameter was determined to be -0.84. Heating enhances the thermal cis-to-trans isomerization and subsequent cooling returned crystals of the trans/trans isomer. Melt, crystallize, and align by light: A macrocyclic compound bearing two azobenzene groups exhibits crystal-liquid-crystal phase transitions on irradiation with UV light (see figure). The photochemically generated crystal underwent reversible phase transitions between the crystal and the mesophase on UV and visible-light irradiation. The molecular order of the randomly oriented crystals could be increased by irradiating with linearly polarized visible light; the value of the order parameter was 0.84.
