618446-60-9Relevant academic research and scientific papers
Radical-polar crossover domino reactions involving organozinc and mixed organocopper/organozinc reagents
Denes, Fabrice,Cutri, Sabrina,Perez-Luna, Alejandro,Chemla, Fabrice
, p. 6506 - 6513 (2008/09/16)
A domino process involving Michael addition and carbocyclization has been developed starting from β-N-allylamino enoates and various organometallic reagents (organozinc halides, diorganozinc reagents, and copper/zinc mixed species). In all cases the mechanism of this domino reaction has been evidenced to involve a radical-polar crossover mechanism.
