61877-80-3

Usage

Uses

Used in Chemical Synthesis:
N,N',N',3-Tetramethyl-3-azapentane-1,5-diamine is used as a building block in the synthesis of various organic compounds, including pharmaceuticals, agrochemicals, and specialty chemicals. Its unique structure and reactivity make it a valuable intermediate in the development of new molecules with specific properties and applications.
Used in Analytical Chemistry:
N,N',N',3-Tetramethyl-3-azapentane-1,5-diamine is used as a regulated fluorescent sensor for transition metal ions. It can form polyazapodands, which are complex structures that can selectively bind and detect specific metal ions. This property makes it useful in environmental monitoring, industrial processes, and research applications where the detection and quantification of metal ions are crucial.
Used in Material Science:
N,N',N',3-Tetramethyl-3-azapentane-1,5-diamine can be used in the development of new materials with unique properties, such as conductive polymers, sensors, and catalysts. Its ability to form stable complexes with metal ions can be exploited to create materials with enhanced performance in various applications.

Upstream product

• 3083-10-1 1,1,4,7,10,10-hexamethyltriethylenetetramine 
• 45278-78-2 2,5,8,11,14,17-hexamethyl-2,5,8,11,14,17-hexaazaoctadecane 
• 3030-47-5 N,N,N',N'',N'''-pentamethyldiethylenetriamine 

Relevant academic research and scientific papers

Basic proline-amide derivatives of GE 2270 and GE 2270-like antibiotics

PCT No. PCT/EP96/00407 Sec. 371 Date Jul. 31, 1997 Sec. 102(e) Date Jul. 31, 1997 PCT Filed Feb. 1, 1996 PCT Pub. No. WO96/24607 PCT Pub. Date Aug. 15, 1996The present invention refers to basic amides derivatives of GE 2270 and GE 2270-like antibiotics of general formula (1), wherein the group GE represents the antibiotic core molecule. The amide derivatives of antibiotic GE 2270 of formula (I) are antimicrobial agents mainly active against gram positive bacteria.

Basic oxazoline-amide derivatives of GE2270 and GE2270-like antibiotics

The present invention refers to basic oxazoline-amide derivatives of GE 2270 and GE 2270-like antibiotics of general formula (I), wherein the group GE represents the antibiotic core molecule. The amide derivatives of antibiotic GE 2270 of formula (I) are antimicrobial agents mainly active against gram positive bacteria. STR1

Reactions of the butyllithiums with tertiary oligoethylenepolyamines

Complexes of t-BuLi monomer with 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTAN, 3-CH3) and tris(N,N-dimethyl-2-aminoethyl)amine (4-CH3) were identified by 13C-NMR. Rapid elimination of LiN(CH2CH2NMe2)2 takes place from the free CH2CH2NMe2 group of t-BuLi·4-CH3. BuLi complexes of hexamethyltriethylenetetramine (5-CH3) and octamethylpenthaethylenehexamine (6) behave similarly, as does 4-CH2Li. Complexes of BuLi oligomers are lithiated at free N-CH3.

N-lithio-N,N',N'',N''-tetramethyldiethylenetriamine and N'-lithio- N,N,N'',N''-tetramethyldiethylenetriamine; oxidative coupling of aminomethyllithium derivatives

N-lithio-N,N',N'',N''-tetramethyldiethylenetriamine (I-Li) is formed from 2,5,8,11-tetramethyl-2,5,8,11-tetraazadodecane (III) or from 2,5,8,11,14,17- hexamethyl-2,5,8,11,14,17-hexaazaoctadecane (IV) with n-BuLi or sec-BuLi, respectively, its isomer N'-lithio-N,N,N'',N'',-tetramethyldiethylene- triamine (II-Li) from tris(2-dimethylaminoethyl)amine (V) with n-BuLi. IV results from treatment of N-lithiomethyl-N,N',N'',N''- tetramethyldiethylenetriamine (PMDTA-Li) with 1,2-dibromoethane.