61886-67-7

Usage

InChI:InChI=1/C19H26/c1-2-3-4-5-6-7-8-11-17-14-15-18-12-9-10-13-19(18)16-17/h9-10,12-16H,2-8,11H2,1H3

Upstream product

• 82408-29-5 phenyl naphthalene-2-carboxylate 
• 626207-32-7 n-nonylzinc bromide 
• 111-83-1 1-bromo-octane 
• 1416982-18-7 N,N,N-trimethyl-1-(naphthalen-2-yl)methanaminium trifluoromethanesulfonate 
• 1070-00-4 trioctylaluminum 
• 858190-38-2 1-(5,6,7,8-tetrahydro-[2]naphthyl)-nonan-1-one 
• 119-64-2 tetralin 
• 764-85-2 Nonanoyl chloride 
• 861013-51-6 1-(naphthalen-2-yl)nonan-1-one 

Relevant academic research and scientific papers

Reductive coupling of benzyl oxalates with highly functionalized alkyl bromides by nickel catalysis

Coupling reactions involving non-sulfonated C-O electrophiles provide a promising method for forming C-C bonds, but the incorporation of functionalized or secondary alkyl groups remains a challenge due to the requirement for well-defined alkylmetal specie

Nickel-catalyzed cross-coupling of aryl or 2-menaphthyl quaternary ammonium triflates with organoaluminum reagents

The cross-coupling of aryltrimethylammonium triflates with AlMe3 and β-H-containing trialkylaluminums was performed in dioxane at 110 °C under catalysis of (dppp)NiCl2 to afford alkylated arenes. The cross-coupling of 2-menaphthyltri

Nickel-Catalyzed C-O Bond-Cleaving Alkylation of Esters: Direct Replacement of the Ester Moiety by Functionalized Alkyl Chains

Two efficient protocols for the nickel-catalyzed aryl-alkyl cross-coupling reactions using esters as coupling components have been established. The methods enable the selective oxidative addition of nickel to acyl C-O and aryl C-O bonds and allow the aryl-alkyl cross-coupling via decarbonylative bond cleavage or through cleavage of a C-O bond with high efficiency and good functional group compatibility. The protocols allow the streamlined, unconventional utilization of widespread ester groups and their precursors, carboxylic acids and phenols, in synthetic organic chemistry.