61923-79-3Relevant academic research and scientific papers
Iron-Catalyzed Carbenoid-Transfer Reactions of Vinyl Sulfoxonium Ylides: An Experimental and Computational Study
Vaitla, Janakiram,Bayer, Annette,Hopmann, Kathrin H.
supporting information, p. 16180 - 16184 (2018/11/23)
A method for the generation of unprecedented vinyl carbenoids from sulfoxonium ylides has been developed and applied in the synthesis of a diverse array of heterocycles such as indolizines, pyrroles, 3-pyrrolin-2-ones, and furans. The reactions proceed by FeBr2 catalysis under mild reaction conditions with a broad substrate scope. A reaction pathway involving iron carbenoids is proposed based on a series of control experiments and DFT calculations.
Iron-catalyzed aerobic C-H functionalization of pyrrolones
Liu, Li-Wei,Wang, Zhen-Zhen,Zhang, Hui-Hui,Wang, Wan-Shu,Zhang, Ji-Zong,Tang, Yu
supporting information, p. 9531 - 9534 (2015/06/08)
The aerobic oxidation of pyrrolones catalyzed by Fe(OTf)3 to form reactive N-acyliminium ion intermediates that undergo nucleophilic additions with alcohols to give the corresponding products in moderate to good yields is described.
