619261-16-4Relevant academic research and scientific papers
Electrocatalytic transformation of malononitrile and cycloalkylidenemalononitriles into spirobicyclic and spirotricyclic compounds containing 1,1,2,2-tetracyanocyclopropane fragment
Elinson,Fedukovich,Vereshchagin,Dorofeev,Dmitriev,Nikishin
, p. 2235 - 2240 (2003)
Electrolysis of malononitrile and cycloalkylidenemalononitriles in EtOH in an undivided cell in the presence of NaBr affords spirobicyclic compounds containing a 1,1,2,2-tetracyanocyclopropane fragment in 50-88% yields.
Functional Group Interconversion of Alkylidenemalononitriles to Primary Alcohols by a Cooperative Redox Operation
Emmetiere, Fabien,Grenning, Alexander J.
, p. 3077 - 3085 (2020/08/10)
Functional group interconversions are essential chemical processes enabling synthesis. In this report, we describe a strategy to convert alkylidenemalononitriles into primary alcohols in one step. The reaction relies on a choreographed redox process invol
Complex Hydroindoles by an Intramolecular Nitrile-Intercepted Allylic Alkylation Cascade Reaction
Vertesaljai, Peter,Ghiviriga, Ion,Grenning, Alexander J.
supporting information, p. 1970 - 1973 (2018/04/16)
Bisnucleophilic reagents derived from malononitrile, ketones, benzaldehydes, and nitromethane can react with bisallylic electrophiles via a nitrile-intercepted allylic alkylation cascade reaction to yield complex hydroindole architectures. Also noteworthy
Photoinduced charge separation in cyclohexylidene-based donor - (σ-bridge) - acceptor compounds - Building blocks for materials
Oosterbaan, Wibren D.,Van Gerven, Paul C. M.,Van Walree, Cornelis A.,Koeberg, Mattijs,Piet, Jacob J.,Havenith, Remco W. A.,Zwikker, Jan W.,Jenneskens, Leonardus W.,Gleiter, Rolf
, p. 3117 - 3130 (2007/10/03)
We describe the syntheses and properties of five semi-rigid donor - (σ-bridge) - acceptor (D-σ-A) compounds. These compounds, which are candidates for incorporation in materials, have aniline-type donors and (mixed) cyano- and alkoxycarbonyl-1,1-difunctio
