61958-13-2Relevant academic research and scientific papers
Three-component reaction of isocyanide with dialkyl acetylenedicarboxylate and alkyl mercaptan: Preparation of new derivatives of stable ketenimines
Sarvary, Afshin,Shaabani, Shabnam,Ghanji, Nasim,Shaabani, Ahmad
, p. 117 - 123 (2015)
Three-component synthesis of stable ketenimines containing a sulfur group based on a capture profile of a zwitterionic intermediate is described. Thus, the reactions of zwitterions, generated from isocyanide and dialkyl acetylenedicarboxylate, react with alkyl mercaptans in CH2Cl2 to afford ketenimines in good yields.
Asymmetric hydrogenation of alkyl(vinyl)thioethers: a promising approach to α-chiral thioethers
Meindertsma, Alex F.,Pollard, Michael M.,Feringa, Ben L.,de Vries, Johannes G.,Minnaard, Adriaan J.
, p. 2849 - 2858 (2008/09/17)
This paper describes the enantioselective hydrogenation of vinylthioethers. We show that thioether derivatives of maleic esters can be hydrogenated with full conversion and up to 60% ee, and that α-thioether cinnamic acids can be hydrogenated in 51% ee with modest conversion.
