61967-80-4Relevant academic research and scientific papers
Free radical rearrangement of alkenyl epoxy silanes. Isolation of α-trimethylsilyl aldehydes
Robertson, Jeremy,Burrows, Jeremy N.
, p. 3777 - 3780 (2007/10/02)
The thiyl-radical induced fragmentation of alkenyl epoxy silanes has been found to afford α-trimethylsilyl aldehydes as the immediate products. These may be isolated, rearranged to trimethylsilyl dienol ethers, or converted to 1,3-dienes with high stereoselectivity.
