6197-08-6Relevant academic research and scientific papers
Magnesium-mediated ortho-Specific Formylation and Formaldoximation of Phenols
Aldred, Robert,Johnston, Robert,Levin, Daniel,Neilan, James
, p. 1823 - 1832 (2007/10/02)
Deprotonation of phenols using magnesium methoxide, followed by distillative removal of free methanol and addition of paraformaldehyde results in ortho-specific magnesium mediated formylation to give the corresponding salicyladehyde magnesium salts, from which the salicylaldehydes can be isolated by acidic work-up.Addition of aq. hydroxylamine sulfate to the salicylaldehyde magnesium salt, in place of the acid work-up, gives the corresponding salicylaldoximes.
Carbonates of acetylenic alcohols
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, (2008/06/13)
Polymerizable carbonate compounds of the formula: wherein A is an aromatic polycycle, R1 and R2 are independently hydrogen atom or alkyl, and n is 1, 2 or 3, are disclosed. They are useful as a component of nonemanating, self-curing and heat resistant resin compositions.
