61990-57-6Relevant academic research and scientific papers
Similarities and differences between azomethines and ketimines: Synthesis, materials characterization and structure of novel imines compounds
Iwan, Agnieszka,Kaczmarczyk, Bozena,Janeczek, Henryk,Sek, Danuta,Ostrowski, Slawomir
, p. 1030 - 1041 (2007)
Imines (ketimines and azomethines) derived from p-dibenzoylbenzene (DB) and terephthalic aldehyde (TA) and two aromatic amines: aniline and 2,6-dimethylaniline have been investigated. Compounds were synthesized via condensation of amines with carbonyl monomers in DMA or amine solution. When using DMA as a solvent, azomethines with high yields were obtained. On the other hand, the amines used as a monomers served also as an effective solvent for the synthesis of the ketanils. This different reactivity of the aldehyde and ketone groups in DMA and in amine depends on the dehydration mechanism being dominated by a kinetic process or thermodynamic one. On the basis of FTIR, 13C and 1H NMR, UV-vis spectra, thermal characteristic and theoretical calculations conclusions are drawn regarding the similarities and differences between azomethines and ketimines. {A figure is presented}.
Two novel push-pull series of benzothiazole-based dyes: Synthesis and characterization
Nourmohammadian, Farahnaz,Gholami, Mahnaz Davoudzadeh
, p. 1548 - 1555 (2012/10/29)
New dichromophoric cyanine dyes based on benzothiazol-2-amines as push-pull systems were synthesized in two series of disperse and cationic forms (see 4 in Scheme1 and 5 in Scheme2, resp.). Their thermal stabilities, UV/VIS, fluorescence, and solvatochrom
METHOD OF PRODUCING IMINES
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Page/Page column 3; 6; 9, (2008/06/13)
A method for forming an imine comprises reacting a first reactant comprising a hydroxyl functionality, a carbonyl functionality, or both a hydroxyl functionality and a carbonyl functionality with a second reactant having an amine functionality in the presence of ordered porous manganese-based octahedral molecular sieves and an oxygen containing gas at a temperature and for a time sufficient for the imine to be produced.
