62007-98-1Relevant academic research and scientific papers
PARTICIPATION D'UN GROUPE AMIDE A LA FORMATION DE SELS DE DIOXOLANNE-1,3 YLIUM-2; MODELE BIOMIMETIQUE DE REACTION DE PEPTIDATION
Mestdagh, Helene,Pancrazi, Ange
, p. 3399 - 3414 (2007/10/02)
An amide group is shown to be capable of intramolecular participation in the formation of an 1,3-dioxolan 2-ylium cation giving a tricyclic organic cation of a new type 5a,b.This cation may be considered as a model of an electrophilic intermediate which m
